Here you can find all the Damon/Elena scenes from the Season 1. I’ll archive only their scene together and not the ones where they’re talking to other characters.

Episode 1.01 – Pilot

Clip 1: Elena sees Damon for the first time at the cemetery.

Episode 1.02 – The Night of the Comet

Clip 1: Elena meets Damon at Stefan’s house and they talk about Katherine, Stefan’s ex.

Episode 1.03 – Friday Night Bites

Clip 1: Damon drops Caroline off at school.
Clip 2: Caroline and Damon crash at the dinner party.
Clip 3: Damon brings Katherine into the conversation when Caroline mention the death of Elena’s parents.
Clip 4: Elena asks Damon who dated Katherine first and she says she’s sorry for his loss, he looks surprised.
Clip 5: Elena dreams she is in her room with Stefan but he turns into Damon.
Clip 6: Damon tries to seduce Elena.
Clip 7: Stefan tries to reach out to Damon about him still punishing Stefan for Katherine’s death.
Clip 8: Damon strokes Elena’s face while she sleeps.

Episode 1.04 – Family Ties
Clip 1: Damon and Stefan get ready for the Founders’ Party.
Clip 2: Elena notices the guest list from the first Founders’ Party, with Damon and Stefan’s names on it.
Clip 3: Damon and Elena talk about the day he and Stefan died.
Clip 4: Damon watches Stefan and Elena dance.
Clip 5: Damon’s words make Elena think and she breaks up with Stefan after he refuses to share anything about himself.
Clip 6: Elena tells Damon to stay away from Caroline.

Episode 1.06 – The Lost Girls
Clip 1: Stefan flashes back to when he and Damon were still best friends and both in love with Katherine.
Clip 2: Damon goes to Elena’s house looking for Stefan.

Episode 1.07 – Haunted
Clip 1: Elena goes to the Salvatore Mansion looking for Stefan and finds Damon instead.
Clip 2: Damon tells a bleeding Elena to leave before he loses control.

Episode 1.08 – 162 Candles
Clip 1: Damon and Elena talk about Stefan having fun with Lexi and what Damon did when he took away Jeremy’s pain.

Episode 1.09 – History Repeating
Clip 1: Damon tries to kill Bonnie after the crystal is destroyed.

Episode 1.11 – Bloodlines
Clip 1: Damon saves Elena from the car crash and the mysterious stranger.
Clip 2: Elena wakes up in the car with Damon, and they’re heading to Georgia.
Clip 3: Damon and Elena arrive at Bree’s bar.
Clip 4: Damon watches through the window while Elena is on the phone with Stefan.
Clip 5: Elena decides to take a time out from life, and it involves alcohol.
Clip 6: Elena saves Damon from a vengeful vampire.
Clip 7: Damon and Elena in the car on the way back home.

Episode 1.12 – Unpleasantville
Clip 1: Elena calls Stefan and Damon answers to his phone.
Clip 2: Damon, Elena and Stefan try to figure out how to kill the new vampire in town.
Clip 3: The trio make their entrance to the party.
Clip 4: Damon invites Elena to dance.
Clip 5: Damon and Stefan kill the other vampire.